Preheat oven to 400ºF.
Sift the all-purpose flour into a large mixing bowl. Add the sugar, baking soda, baking powder, ground cinnamon, salt, and instant coffee granules and stir to incorporate.
In a medium mixing bowl, add the chilled espresso, two eggs, milk, vanilla extract, and maple syrup. Use an electric mixer to whisk until combined.
Pour the wet ingredients into the dry ingredients and use the electric mixer to beat until combined. The batter should be a very thick but still maintain a liquid consistency.
Pour the batter into a 4-cup liquid measuring cup with a spout. This will make it easier to pour the batter into the muffin tins.